In Situ Curing Technology for Dual Ceramic Composed by Organic–Inorganic Functional Polymer Gel Electrolyte for Dendritic-Free and Robust Lithium–Metal Batteries. Besides, the battery assembled of LiFePO 4 /PEO + 10% LATP + 20% LLTO/Li exhibits superior cyclic stability with high Coulombic efficiency. This study recommends that the
View moreIn situ UV-cured composite electrolytes for highly efficient quasi-solid-state lithium ion batteries with wide Li 10.7 Al 0.24 La 3 Zr 2 O 12 for quasi-solid-state lithium-ion batteries was designed and synthesized via solvent-free in situ
View moreSolid polymer electrolytes (SPEs) are expected to possess high ionic conductivity and conformal interfacial contact with all cell components for all-solid-state lithium-ion batteries. However, the commonly used in situ separator
View moreThe in situ ring-opening polymerization of cyclic ether monomers not only simplifies the battery manufacturing process but also improves the solid/solid interfacial contacts between electrolytes and
View moreDownload Citation | High Conductive Composite Polymer Electrolyte via in Situ UV-Curing for All-Solid-State Lithium Ion Batteries | All-solid-state lithium ion batteries are considered to be one
View moreIn-situ curing poly(N,N''-Methylenebisacrylamide)-based composite electrolyte reinforced with high-strength glass fiber skeleton for solid state lithium ion batteries Author links open overlay panel Yuxiang Zhang a, Shijie Lu a, Zhikun Zhao a, Xinyu Zhang a, Haijian Lv a, Zhuolin Yang a, Wenbin Sun b, Man Xie a, Daobin Mu a
View moreThe all-solid-state LiFePO 4 /Li cell displays a high discharge capacity of 147 mAh g –1 and good capacity retention of ∼82% in 100 cycles under 0.1 C at room temperature. The strategy for in situ fabrication of a
View moreConstruction of high-performance solid-state electrolytes for lithium metal batteries by UV-curing technology. Author links open overlay panel Zengxu were prepared by solution flow casting and UV-irradiated in situ polymerization. polarization of PP15-30-SCN was significantly reduced, and the battery cycled stably at current
View moreIn situ-curing a thin layer SSE on a lithium iron phosphate (LFP) composite cathode reduces the SSE/cathode interfacial resistance. An LFP/SSE/Li ASSLiMB yields specific discharge capacity of 147.8 mAh·g −1 and retains 131.9 mAh·g −1 after 200 charge/discharge cycles. Direct observation demonstrates that strong binding of the in situ
View moreHighlights • High-performance solid electrolytes prepared using UV-curing technology. • PP15-30-SCN exhibits nearly a 40-fold increase in ionic conductivity compared
View moreThe safety concerns associated with power batteries have prompted significant interest in all−solid−state lithium batteries (ASSBs). However, the advancement of
View moreIn situ-curing a thin layer SSE on a lithium iron phosphate (LFP) composite cathode reduces the SSE/cathode interfacial resistance. An LFP/SSE/Li ASSLiMB yields
View moreInterfacial Ionic Conductivity and Cyclic Performance of Lithium Metal Battery Using In-Situ Polymerized Poly(Vinylene Carbonate)-Li6.4ga0.2la3zr1.4o12 Solid Electrolytes. (PVC) - Li6.4Ga0.2La3Zr2O12(LLZO) composite electrolyte prepared by in-situ curing technology forms a tight interfacial contact through in-situ curing, reducing the
View moreA polycarboxylic/ether composite polymer electrolyte via in situ UV-curing for all-solid-state lithium battery. A polycarboxylic/ether composite polymer electrolyte via in situ UV-curing for all-solid-state lithium battery;
View moreHerein, a novel IPCE based on a Norland optical adhesive (NOA81) and a Li-rich fast ion conductor Li 10.7 Al 0.24 La 3 Zr 2 O 12 for quasi-solid-state lithium-ion batteries was designed and synthesized via solvent-free in situ ultraviolet (UV)
View moreThe invention relates to the technical field of electrolyte, and discloses an in-situ curing electrolyte, a gel lithium ion battery and a preparation method thereof. The in-situ curing electrolyte comprises 100 parts by weight of solvent, 0.2-1.2 parts by weight of lithium salt calculated by the mass of lithium element, 2-10 parts by weight of electropolymerization monomer and 1-10 parts by
View moreDOI: 10.2139/ssrn.4363504 Corpus ID: 257048386; In Situ Curing Enables High Performance All-Solid-State Lithium Metal Batteries Based on Ultrathin-Layer Solid Electrolytes
View moreIn situ-curing a thin layer SSE on a lithium iron phosphate (LFP) composite cathode reduces the SSE/cathode interfacial resistance. An LFP/SSE/Li ASSLiMB yields
View moreLi salt-initiated cationic ring-opening polymerization (CROP) is a promising method to prepare in-situ PEs and avoid the above-mentioned problems [37] CROP, Li salts, including LiPF 6 [38], [39], LiDFOB [33], [34], and LiBF 4, can be used as initiators to initiate the CROP of monomers, such as 1,3-dioxolane (DOL) and 1,3,5-trioxane (TXE), which avoids the introduction of
View moreDesigning advanced solid-state sodium batteries (SSBs) demands simultaneously overcoming the low ionic conductivity of solid-state electrolytes (SSEs) and the poor interfacial compatibility between electrodes and SSEs. Herein, a composite solid-state electrolyte (CSE) with high ionic conductivity was prepared by using an efficient UV
View moreAll-Solid-State Lithium Batteries (ASSLBs) are a new type of lithium battery technology that offers higher energy density and superior safety compared to traditional liquid electrolyte lithium-ion batteries (LIBs), as well as the ability to be used over a wide temperature range [[3], [4], [5]]. Among them, solid-state electrolytes, as a crucial component of ASSLBs,
View moreIn situ-curing a thin layer SSE on a lithium iron phosphate (LFP) composite cathode reduces the SSE/cathode interfacial resistance. An LFP/SSE/Li ASSLiMB yields specific discharge capacity of 147.8 mAh·g −1 and retains 131.9 mAh·g −1 after 200 charge/discharge cycles. Direct observation demonstrates that strong binding of the in situ
View moreAn Industrial Perspective and Intellectual Property Landscape on Solid-State Battery Technology with a Focus on Solid-State Electrolyte Chemistries. Batteries 2024, 10 (1) In Situ Curing Technology for Dual
View moreIn situ-curing a thin layer SSE on a lithium iron phosphate (LFP) composite cathode reduces the SSE/cathode interfacial resistance. An LFP/SSE/Li ASSLiMB yields specific discharge
View moreBesides, the battery assembled of LiFePO4/PEO + 10% LATP + 20% LLTO/Li exhibits superior cyclic stability with high Coulombic efficiency. This study recommends that the binary network
View moreThe formation of the solid electrolyte interphase (SEI) at the SE/anode interface was monitored via XPS equipped with an in-situ lithium deposition system (Figure 2) designed
View moreIn this work, we investigate an in situ building method of a solid electrolyte, which constructs a composite electrolyte on the cathode by UV-curing and reduces the interfacial impedance by 69.1%. The solid electrolyte shows a decent ionic conductivity of 2.21 × 10–5 S cm–1 at 25 °C and presents a wide electrochemical stability window (>4.7 V vs Li+/Li).
View moreIn Situ Curing Technology for Dual Ceramic Composed by Organic–Inorganic Functional Polymer Gel Electrolyte for Dendritic-Free and Robust Lithium–Metal Batteries. Besides, the battery assembled of LiFePO
View moreUV-Initiated Soft–Tough Multifunctional Gel Polymer Electrolyte Achieves Stable-Cycling Li-Metal Battery. Wei Fan. Wei Fan. School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China In Situ Curing Technology for Dual Ceramic Composed by Organic–Inorganic Functional Polymer
View moreAn in situ-curing 3D printing technology was developed, which comprised resin impregnation, 3D printing/pre-curing and post-curing processes. Continuous carbon fiber-reinforced thermosetting phenolic resin (CF/PF) composites were fabricated based on that. The selection of pre-curing temperature was the key to successful printing.
View moreIn this work, an in-situ freeze-drying technology is unprecedentedly used to uniformly coat halide SE (LIC) layer on LCO cathode surface to realize the above goal. The
View moreThe pressing need to circumvent the negative impact of human activities on the environment has escalated the demand for electrochemical energy storage devices with an ever-growing energy density. Among the technologies, metal–sulfur and metal–air batteries appear to be promising owing to (i) less dependence on rare metals such as electrode materials, (ii) low
View moreIn Situ Curing Technology for Dual Ceramic Composed by Organic–Inorganic Functional Polymer Gel Electrolyte for Dendritic‐Free and Robust Lithium–Metal Batteries Besides, the battery assembled of LiFePO 4 /PEO + 10% LATP + 20% LLTO/Li exhibits superior cyclic stability with high Coulombic efficiency. This study recommends that the
View moreIn this work, an in-situ freeze-drying technology is unprecedentedly used to uniformly coat halide SE (LIC) layer on LCO cathode surface to realize the above goal. High-areal-capacity and long-cycle-life all-solid-state battery enabled by freeze drying technology. Energy Environ. Sci. (2023), 10.1039/d3ee00420a. Google Scholar [17]
View moreTo facilitate better in-situ curing and self-healing effects underwater, LPTM-55 with higher viscosity and improved flow properties was selected as the optimal material for subsequent studies. Additionally, cyclic tensile tests were conducted at a constant rate of 100 mm/min with a fixed load corresponding to 150% strain ( Figure 2 d).
View moreIn situ-curing a thin layer SSE on a lithium iron phosphate (LFP) composite cathode reduces the SSE/cathode interfacial resistance. An LFP/SSE/Li ASSLiMB yields specific discharge capacity of 147.8 mAh·g-1 and retains 131.9 mAh·g-1 after 200 charge/discharge cycles. Direct observation demonstrates that strong binding of the in situ-cured SSE
View moreplatform for in situ characterization. We suggest and emphasize some future directions for SSBs. First, different in situ or operando characterization techniques should be developed and combined to track the real-time composition and structure changes at the interfaces in SSBs. Second, in addition to metal ions, metal-air and metal-sulfur
View moreIn this study, within a very short time of 30 s, a SIL turns immobile using efficient and controllable UV-curing with an ethoxylated trimethylolpropane triacrylate (ETPTA) network, forming a homogeneous SIL
View moreHe, Linchun and Ye, Hualin and Sun, Qiaomei and Tieu, Aaron Jue Kang and Lu, Li and Liu, Zishun and Adams, Stefan, In Situ Curing Enables High Performance All-Solid-State Lithium Metal Batteries Based on Ultrathin-Layer Solid Electrolytes.
The strategy for in situ fabrication of a composite polymer electrolyte shows a promising way for the application of all-solid-state lithium batteries. To access this article, please review the available access options below. Read this article for 48 hours. Check out below using your ACS ID or as a guest.
All-solid-state lithium ion batteries are considered to be one of the best candidates for next generation batteries due to the high safety and energy density, but there is still a severe challenge for seeking the high-performance solid electrolytes with high ionic conductivity.
Fig. 1 a depicts the in situ freeze-drying coating process in which the raw materials (LiCl and InCl 3) are weighed at stoichiometric molar ratios and then dissolved in deionized water. Then, the positive active material LCO with the desired amount of coating is added to the precursor solution and stirred to form a evenly distributed solution.
All solid-state lithium metal batteries (ASSLiMB) containing nonflammable and thermally stable solid-state electrolytes (SSE) are commonly regarded as promising next-generation batteries with the potential to replace Li-ion batteries that rely on liquid electrolytes.
The use of lithium metal negative electrodes and solid electrolytes (SEs) in all solid-state batteries (ASSBs) is expected to completely solve the problems of low energy density and poor safety of existing batteries. , , . Numeric SEs have been discovered/reported, including many oxides, sulfides, and halides .
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